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The IUPAC nomenclature of organic chemistry uses the numerical prefixes derived from Greek, except for the prefix for 9 (as mentioned) and the prefixes from 1 to 4 (meth-, eth-, prop-, and but-), which are not derived from words for numbers.

These prefixes were invented by the IUPAC, deriving them from the pre-existing names for several compounds that it was intended to preserve in the new system: 

https://english.stackexchange.com/questions/28372/why-meth-eth-prop-when-there-is-uni-di-tri